Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

JET-LUBE API-MODIFIED & API-SILICONE GREASE

NFPA

PRODUCT USE

Petroleum- based lubricating grease for tubing, casing and line pipe.

SYNONYMS

Petroleum-based, lubricating, grease, tubing, casing, line, pipe

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

May cause CANCER.
Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic
environment.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual.  A metallic taste, nausea, vomiting and burning feeling in the upper stomach region occur after ingestion of copper and its derivatives. The vomitus is usually green/blue and discolors contaminated skin. Acute poisonings from ingestion are rare due to their prompt removal by vomiting. Should vomiting not occur, or is delayed systemic poisoning may occur producing kidney and liver damage, wide-spread capillary damage, and be fatal; death may occur after relapse from an apparent recovery. Anemia may occur in acute poisoning.  

EYE

  If applied to the eyes, this material causes severe eye damage.  

SKIN

  The liquid may be miscible with fats or oils and may degrease the skin, producing a skin reaction described as non-allergic contact dermatitis. The material is unlikely to produce an irritant dermatitis as described in EC Directives .  The material may accentuate any pre-existing dermatitis condition.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  

INHALED

  Inhalation may produce health damage*.  Inhalation hazard is increased at higher temperatures.  The material is not thought to produce respiratory irritation (as classified using animal models). Nevertheless inhalation of the material, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.  Inhalation of oil droplets/ aerosols may cause discomfort and may produce chemical pneumonitis.  Inhalation of freshly formed zinc oxide particles sized below 1.5 microns and generally between 0.02 to 0.05 microns may result in "metal fume fever", with symptoms resembling influenza. Symptoms may be delayed for up to 12 hours and begin with the sudden onset of thirst, and a sweet, metallic or foul taste in the mouth. Other symptoms include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalised feeling of malaise. Mild to severe headache, nausea, occasional vomiting, fever or chills, exaggerated mental activity, profuse sweating, diarrhoea, excessive urination and prostration may also occur. Tolerance to the fumes develops rapidly, but is quickly lost. All symptoms usually subside within 24-36 hours following removal from exposure. Leucocytosis, a transient increase in white blood cell counts, is reported as a common finding in metal fume fever but is not known to be common amongst welders. Severe over-exposure to zinc oxide, following inhalation of fumes or finely divided dusts may result in bronchitis or pneumonia; a bluish skin tint may be present.  Inhalation of dusts, generated by the material during the course of normal handling, may be damaging to the health of the individual.  Copper poisoning following exposure to copper dusts and fume may result in headache, cold sweat and weak pulse. Capillary, kidney, liver and brain damage are the longer term manifestations of such poisoning. Inhalation of freshly formed metal oxide particles sized below 1.5 microns and generally between 0.02 to 0.05 microns may result in "metal fume fever". Symptoms may be delayed for up to 12 hours and begin with the sudden onset of thirst, and a sweet, metallic or foul taste in the mouth. Other symptoms include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalised feeling of malaise. Mild to severe headache, nausea, occasional vomiting, fever or chills, exaggerated mental activity, profuse sweating, diarrhoea, excessive urination and prostration may also occur. Tolerance to the fumes develops rapidly, but is quickly lost. All symptoms usually subside within 24-36 hours following removal from exposure.  

CHRONIC HEALTH EFFECTS

  Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical systems.  There is ample evidence that this material can be regarded as being able to cause cancer in humans based on experiments and other information.  There is some evidence that human exposure to the material may result in developmental toxicity. This evidence is based on animal studies where effects have been observed in the absence of marked maternal toxicity, or at around the same dose levels as other toxic effects but which are not secondary non-specific consequences of the other toxic effects.  Ample evidence from experiments exists that there is a suspicionthis material directly reduces fertility.  Oil may contact the skin or be inhaled. Extended exposure can lead to eczema, inflammation of hair follicles, pigmentation of the face and warts on the soles of the feet. Exposure to oil mists can cause asthma, pneumonia and scarring of the lungs. Oils have been linked to cancer of the skin and scrotum. Compounds that are less viscous and with smaller molecular weights are more dangerous. There may be liver damage and the lymph nodes may be affected; heart inflammation can also occur at high doses.  Repeated application of mildly hydrotreated oils (principally paraffinic), to mouse skin, induced skin tumors; no tumors were induced with severely hydrotreated oils.  High boiling residues of petroleum process can produce both benign and malignant skin tumors, according to animal testing. They may contain significant concentrations of polynuclear aromatic hydrocarbons (PAHs).