Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

UNION CARBIDE MOLECULAR SIEVE TYPE 4ADG

NFPA

PRODUCT USE

Zeolites are the aluminosilicate members of the family of microporous solids known as "
molecular sieves" . The term refers to a particular property of these materials, i.e. the
ability to selectively sort molecules based primarily on a size exclusion process. This is
due to a very regular pore structure of molecular dimensions. The maximum size of the
molecular or ionic species that can enter the pores of a zeolite is controlled by the
diameters of the tunnels. These are conventionally defined by the ring size of the
aperture, where, for example, the term " 8ring" refers to a closed loop that is built from
8 tetrahedrally coordinated silicon (or aluminium) atoms and 8 oxygen atoms. These rings
are not always perfectly flat and symmetrical due to a variety of effects, including
strain induced by the bonding between units that are needed to produce the overall
structure, or coordination of some of the oxygen atoms of the rings to cations within the
structure. Therefore, the pore openings for all rings of one size are not identical. More
than 1500 zeolites types of been synthesized and 48 naturally occurring zeolites are
known. They are basically hydrated aluminosilicates with an " open" structure that can
accommodate a wide variety of cations such as Na⁺, K⁺, Ca²⁺, Mg²⁺ and others. These
positive ions are rather loosely held and can readily be exchanged for others in a contact
solution. As a desiccant and adsorbent for the drying and purification of gases and
liquids; for selective molecular separations based on size and polar properties; as ion
exchangers; as chemical carriers and in gas chromatography. Also used for water softening;
as detergent builders; in the production of oxygen from air; in the petroleum industry to
remove normal paraffins from distillates; to separate p- xylenes; in fluid catalytic
cracking and hydrocracking catalysts.

SYNONYMS

"Molecular Sieve Type 4 ADG", "Molecular Sieve 4ADG", "sodium alumino silicate", "sodium
silicoaluminate", "sodium aluminium silicate", zeolite, "synthetic zeolites", "natural
zeolites", clathrates, "Molecular Sieves Union Carbide 4ADG", "Sieves Union Carbide 4ADG",
"drying agent Union Carbide 4ADG", Na2-O.Al2-O3.Si-O2, Al2-Na2-Si-O4, Al-Na-Si-O4

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Not normally a hazard due to the physical form of product. The material is a physical irritant to the gastrointestinal tract.  The material has NOT been classified as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality (death) rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, unintentional ingestion is not thought to be cause for concern.  

EYE

  Dehydrated zeolites may cause thermal burns with corneal damage.  Although the material is not thought to be an irritant, direct contact with the eye may cause transient discomfort characterized by tearing or conjunctival redness (as with windburn). Slight abrasive damage may also result. The material may produce foreign body irritation in certain individuals.  

SKIN

  Dehydrated zeolites generate heat in contact with moisture and may produce thermal burns.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  The material is not thought to produce adverse health effects or skin irritation following contact (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.  

INHALED

  Intratracheal instillation of one species of zeolite, mordenite, in rats produced a mild fibrosis and hyperplasia. No significant pulmonary inflammation or interstitial fibrosis was seen in inhalation studies.  The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.  

CHRONIC HEALTH EFFECTS

  All workers involved in the production and use of zeolite-containing products are potentially exposed to erionite, a fibrous form of zeolite, which is mined with deposits of other zeolites. When administered by inhalation erionite induced pleural mesotheliomas in rats of both sexes. When administered by intraperitoneal injection, erionite induced peritoneal mesotheliomas in male mice. When introduced by intrapleural injection erionite induced pleural mesotheliomas in male and female rats.  Descriptive studies have demonstrated a very high mortality from malignant mesotheliomas, mainly of the pleura, in three Turkish villages where there has been contamination from erionite and where the population had been exposed from birth. Erionite fibres were identified in lung tissue samples in cases of pleural mesotheliomas; ferruginous bodies were found in a much higher proportion of inhabitants in contaminated villages than those of control villages.  Intratracheal instillation of another species of zeolite, mordenite, in rats, produced a mild fibrosis and hyperplasia. No significant pulmonary inflammation or interstitial fibrosis was seen in inhalation studies. Mordenite exhibits low cytotoxicity, in vitro.  A sample of natural zeolite particles induced aberrant metaphase in human whole blood cultures in vitro. This zeolite sample also induced aberrant metaphases in cells collected by peritoneal lavage of mice after intraperitoneal injection.  There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.