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VANADIUM MSDS报告[下载][中文版]

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

VANADIUM

NFPA

Flammability 0
Toxicity 2
Body Contact 2
Reactivity 2
Chronic 2
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

PRODUCT USE

Target material for x- rays, manufacture of alloy steels, vanadium compounds, especially
catalyst for sulfuric acid and synthetic rubber. Found in many minerals including
patronite (polysulfide), vanadinite, roscoelite and carnotite.

SYNONYMS

V, V, "vanadium metal"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

None

EMERGENCY OVERVIEW

RISK

Harmful to aquatic organisms.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Accidental ingestion of the material may be damaging to the health of the individual.  Vanadium poisoning causes immediate distress with nose bleeds, severe diarrhea, paralysis of the legs, breathing difficulties, convulsions and death. The liver and kidneys may degenerate, and sometimes there can be bleeding from the lung and adrenal cortex. Vanadium is about as toxic as arsenic.  

EYE

  There is some evidence to suggest that this material can causeeye irritation and damage in some persons.  Contact with the eye, by metal dusts, may produce mechanical abrasion or foreign body penetration of the eyeball.  

SKIN

  The material is not thought to produce adverse health effects or skin irritation following contact (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  

INHALED

  Inhalation may produce health damage*.  The material is not thought to produce respiratory irritation (as classified using animal models). Nevertheless inhalation of dusts, or fume, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.  Inhalation of dusts, generated by the material during the course of normal handling, may be damaging to the health of the individual.  Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disability if excessive concentrations of particulate are inhaled.  The inhalation of small particles of metal oxide results in sudden thirst, a sweet, metallic our foul taste, throat irritation, cough, dry mucous membranes, tiredness and general unwellness. Headache, nausea and vomiting, fever or chills, restlessness, sweating, diarrhea, excessive urination and prostration may also occur. After exposure is removed, recovery occurs within 24-36 hours.  The inhalation of vanadium dust can cause irritation of the respiratory tract and eyes, with cough, wheezing, bronchitis, phlegm with blood stains, and blackening of the tongue. Internal symptoms may include loss of appetite, anemia, nausea, headache, sleep difficulties, nervousness, dizziness, kidney damage, tremor, psychic disturbances and blindness.  

CHRONIC HEALTH EFFECTS

  There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.  Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.  Vanadium is an essential trace element. Poisoning can cause stomach upset,emphysema and wheezing.  Metallic dusts generated by the industrial process give rise to a number of potential health problems. The larger particles, above 5 micron, are nose and throat irritants. Smaller particles however, may cause lung deterioration. Particles of less than 1.5 micron can be trapped in the lungs and, dependent on the nature of the particle, may give rise to further serious health consequences.  
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