Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

VALSPAR ANZOTHANE LEAD CONTAINING 450-LINE

NFPA

PRODUCT USE

Part A or Base of a 2 pack urethane coating system. Requires that the two parts be mixed
by hand or mixer before use, in accordance with manufacturers directions. Mix only as much
as is required. Do not return the mixed material to the original containers. Refer also to
protective measures for the other component used with the product. Read both MSDS before
using; store and attach MSDS together. The material when ready for use, i.e. with 2 parts
mixed together, CONTAINS free organic isocyanate. Application requires control measures,
special precautions and use of personal protective gear. [APMF].

SYNONYMS

"Lead chrome colours Part A Base Flexible polyurethane gloss coating"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Danger of cumulative effects.
May cause SENSITIZATION by skin contact.
Limited evidence of a carcinogenic effect.
May cause harm to the unborn child.
Possible risk of impaired fertility.
HARMFUL - May cause lung damage if swallowed.
Harmful: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.
Highly flammable.
Vapors may cause dizziness or suffocation.
Very toxic to aquatic organisms, may cause long- term adverse effects in the
aquatic environment.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual.  Not a likely route of entry into the body in commercial or industrial environments. The liquid may produce considerable gastrointestinal discomfort and be harmful or toxic if swallowed. Ingestion may cause nausea, pain and vomiting. Vomit entering the lungs by aspiration can cause inflammation of the lungs, which can lead to death.  

EYE

  This material can cause eye irritation and damage in some persons.  The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of vision, if not promptly and adequately treated.  The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  Skin contact with the material may be harmful; systemic effects may resultfollowing absorption.  This material can cause inflammation of the skin oncontact in some persons.  The liquid may produce skin discomfort following prolonged contact. Defatting and/or drying of the skin may lead to dermatitis.  Toxic effects may result from skin absorption.  Bare unprotected skin should not be exposed to this material.  The material may accentuate any pre-existing skin condition.  The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.  

INHALED

  The material is not thought to produce respiratory irritation (as classified using animal models). Nevertheless inhalation of the material, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.  Inhalation hazard is increased at higher temperatures.  Sensitization reactions may appear suddenly after repeatedsymptom free exposures.  Inhalation of vapor may aggravate a pre-existing respiratory condition.  Respiratory sensitization may result in allergic/asthma like responses; from coughing and minor breathing difficulties to bronchitis with wheezing, gasping.  Inhalation of high concentrations of gas/vapor causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination.  If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death.  

CHRONIC HEALTH EFFECTS

  There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.  Skin contact with the material is more likely to cause a sensitization reaction in some persons compared to the general population.  Ample evidence exists that developmental disorders are directlycaused by human exposure to the material.  

  Principal routes of exposure are usually by inhalation of vapor/spray mist and skin contact with the liquid.  Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].  Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitized persons should not be allowed to work in situations where exposure may occur.  Prolonged or continuous skin contact with the liquid may cause defatting with drying, cracking, irritation and dermatitis following.  Lead, in large amounts, can affect the blood, nervous system, heart, glands, immune system and digestive system. Anemia may occur. If untreated muscles may become paralyzed, and there may be brain damage. Symptoms include joint and muscle pain, weakness in the back of the forearm and wrist and in the shin muscles, headaches, dizziness, abdominal pain, diarrhea or constipation, nausea, vomiting, blue line on gums, sleep disturbance and a metallic taste in the mouth. The pressure in the brain may increase with high doses,  and cause brain damage, coma, and death. Early signs include loss of appetite and weight, constipation, tiredness and irritability, headache, weakness. Later there may be vomiting,  nervousness, and muscle pains in the arms and legs. Serious cases cause severe vomiting, inco-ordination, stupor, permanent eye damage, high blood pressure, multiple nerve disorders of the head resulting in paralysis and loss of reflexes, delirium, convulsions and coma. The kidneys may become irreversibly damaged, and the nervous system may become affected causing mental retardation, cerebral palsy, and jerks and seizures.  Lead can accumulate in the skeleton for a very long time.  Lead is a cumulative poison with adverse effects in pregnancy [NIOSHTIC].