Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

VALSPAR SUPER ANZOPON FLUID RESIST PRIMER GREEN 666-2001

NFPA

PRODUCT USE

Base or Part A of a 2 pack epoxy coating system. Requires that the two parts be mixed by
hand or mixer before use, in accordance with manufacturers directions. Mix only as much as
is required. Do not return the mixed material to the original containers. Application is
usually by spray atomisation. The use of a quantity of material in an unventilated or
confined space may result in increased exposure and an irritating atmosphere
developing.Before starting consider control of exposure by mechanical ventilation. SAFETY
DIRECTIONS Handling and usage of this product must be carried out under well ventilated
conditions that prevent inhalation of vapor and spray mist Prevent skin contact by wearing
impervious gloves. Wear a positive pressure air supplied full face respirator whilst
spraying and until all spray mist has effectively been dispersed. Breathing of vapor or
spray mist is harmful and may cause lung irritation and allergic respiratory reaction
[NHMRC].

SYNONYMS

"aircraft Epoxy spray primer Base Component strontium chromate Anzepon"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Risk of serious damage to eyes.
May cause CANCER.
May cause SENSITIZATION by skin contact.
HARMFUL - May cause lung damage if swallowed.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to respiratory system and skin.
Highly flammable.
Vapors may cause dizziness or suffocation.
Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic
environment.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual.  Not a likely route of entry into the body in commercial or industrial environments. The liquid may produce considerable gastrointestinal discomfort and be harmful or toxic if swallowed. Ingestion may cause nausea, pain and vomiting. Vomit entering the lungs by aspiration can cause inflammation of the lungs, which can lead to death.  

EYE

  If applied to the eyes, this material causes severe eye damage.  The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  Skin contact with the material may be harmful; systemic effects may resultfollowing absorption.  This material can cause inflammation of the skin oncontact in some persons.  Bare unprotected skin should not be exposed to this material.  Epoxy materials may cause allergic and/or contact dermatitis responses, which may occur on exposure or may become apparent only after repeated exposures. Sensitization is possible. Photoallergic dermatitis may result from contact with the material. This type of response can be elicited only in individuals who have been previously allergically sensitized to the chemical agent and appropriate radiation. Photoallergic dermatitis presents, clinically, as an eczematous dermatitis in sun-exposed areas.  Sensitization may result in allergic dermatitis responses includingrash, itching, hives or swelling of extremities.  Sensitization reactions may appear suddenly after repeatedsymptom free exposures.  Toxic effects may result from skin absorption.  Exposure limits with "skin" notation indicate that vapor and liquid may be absorbed through intact skin. Absorption by skin may readily exceed vapor inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may also invalidate the exposure standard.  The material may accentuate any pre-existing dermatitis condition.  The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.  

INHALED

  If inhaled, this material can irritate the throat andlungs of some persons.  Inhalation of high concentrations of gas/vapor causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination.  If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death.  Inhalation of vapor may aggravate a pre-existing respiratory condition such as asthma, bronchitis, emphysema.  

CHRONIC HEALTH EFFECTS

  Skin contact with the material is more likely to cause a sensitization reaction in some persons compared to the general population.  There is ample evidence that this material can be regarded as being able to cause cancer in humans based on experiments and other information.  

  Principal routes of exposure are usually by inhalation of vapor/spray mist and skin contact with the material.  Chromium VI exposures have been related to higher incidence of lung cancer.  Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].  Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitized persons should not be allowed to work in situations where exposure may occur.  Prolonged or continuous skin contact with the liquid may cause defatting with drying, cracking, irritation and dermatitis following.  Welding or flame cutting of metals with chromate pigmented primers or coatings may result in inhalation of highly toxic chromate fumes. Exposures may be significant in enclosed or poorly ventilated areas.