Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

WAPROO RAVEN OIL

NFPA

PRODUCT USE

The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing.Before starting consider
control of exposure by mechanical ventilation. Shoe dye. Applied by pad or may be sprayed.
Requires use of sealer for durable finish.

SYNONYMS

"shoe colour dye ethanol industrial alcohol based"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Irritating to eyes.
Highly flammable.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Accidental ingestion of the material may be damaging to the health of the individual.  Ingestion of ethanol (ethyl alcohol, "alcohol") may produce nausea, vomiting, bleeding from the digestive tract, abdominal pain, and diarrhea. Effects on the body:  
Blood concentration
Effects
<1.5 g/L
Mild: impaired vision, co-ordination and reaction time; emotional instability
1.5-3.0 g/L
Moderate: Slurred speech, confusion, inco-ordination, emotional instability, disturbances in perception and senses, possible blackouts, and impaired objective performance in standardized tests. Possible double vision, flushing, fast heart rate, sweating and incontinence. Slow breathing may occur rarely and fast breathing may develop in cases of metabolic acidosis, low blood sugar and low blood potassium. Central nervous system depression may progress to coma.
3-5 g/L
Severe: cold clammy skin, low body temperature and low blood pressure. Atrial fibrillation and heart block have been reported. Depression of breathing may occur, respiratory failure may follow serious poisoning, choking on vomit may result in lung inflammation and swelling. Convulsions due to severe low blood sugar may also occur. Acute liver inflammation may develop.
  
  .  

EYE

  There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation. Severe inflammation may be expected with pain. There may be damage to the cornea. Unless treatment is prompt and adequate there may be permanent loss of vision. Conjunctivitis can occur following repeated exposure.  Direct contact of the eye with ethanol may cause immediate stinging and burning with reflex closure of the lid and tearing, transient injury of the corneal epithelium and hyperaemia of the conjunctiva. Foreign-body type discomfort may persist for up to 2 days but healing is usually spontaneous and complete.  The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay of some time. Repeated exposure can cause contact dermatitis which is characterized by redness, swelling and blistering.  Skin contact is not thought to have harmful health effects, however the material may still produce health damage following entry through wounds, lesions or abrasions.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.  

INHALED

  Inhalation may produce health damage*.  Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the individual.  There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage.  Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, reduced alertness, loss of reflexes, lack of coordination and vertigo.  The most common signs of inhalation overexposure to ethanol, in animals, include ataxia, incoordination and drowsiness for those surviving narcosis. The narcotic dose for rats, after 2 hours of exposure, is 19260 ppm.  Inhalation of high concentrations of gas/vapor causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination.  

CHRONIC HEALTH EFFECTS

  Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.  Prolonged exposure to ethanol may cause damage to the liver and cause scarring. It may also worsen damage caused by other agents. Large amounts of ethanol taken in pregnancy may result in "fetal alcohol syndrome", characterized by delay in mental and physical development, learning difficulties, behavioral problems and small head size. A small number of people develop allergic reactions to ethanol, which include eye infections, skin swelling, shortness of breath, and itchy rashes with blisters.