Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

KONICA KONICADOL TYPE 651K, REPLENISHER & WORKING SOLUTION

NFPA

PRODUCT USE

Photographic developer solution. A slightly alkaline reducing solution which may evolve
sulfur dioxide upon reaction with strong acids.

SYNONYMS

"photographic chemical", "developer for RST System Film"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Irritating to eyes.
May cause SENSITIZATION by skin contact.
Limited evidence of a carcinogenic effect.
Possible risk of irreversible effects.
Toxic to aquatic organisms.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following ingestion, especially where pre-  existing organ (e.g. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality (death) rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern.  Considered an unlikely route of entry in commercial/industrial environments.  

EYE

  This material can cause eye irritation and damage in some persons.  The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  The material is not thought to produce adverse health effects or skin irritation following contact (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.  Sensitization may result in allergic dermatitis responses includingrash, itching, hives or swelling of extremities.  

INHALED

  The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.  No toxic effects evident.  

CHRONIC HEALTH EFFECTS

  There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.  Skin contact with the material is more likely to cause a sensitization reaction in some persons compared to the general population.  

  Principal routes of exposure are usually by eye contact skin contact.  Skin contact can cause itching, burning and inflammation and repeated or  prolonged contact may result in dermatitis. Inhalation of mists containing  potassium carbonate may produce irritation of the nose and throat,  resulting in coughing, sneezing, and difficulty breathing.  Long term frequent exposure to hydroquinone vapour increases the risk of  lung oedema.  Diethylene glycol absorption, if frequent and long term, may cause damage  to the nervous system, liver and kidneys.