Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

TALL OIL ACIDS, N-OLEYL-1,3-PROPANEDIAMINE/ FORMALDEHYDE

NFPA

PRODUCT USE

In oil- based antifoulant.

SYNONYMS

"fatty acids, tall oil, reaction products with formaldehyde and(Z)-N-9-octadecenyl-1, 3-
propanediamine", "fatty acids, tall oil, reaction products with formaldehyde and(Z)-N-9-
octadecenyl-1, 3-propanediamine", "tall oil fatty acids, N-oleyl-1, 3-diaminopropane,
formaldehyde condensate", "tall oil fatty acids, N-oleyl-1, 3-diaminopropane,
formaldehyde condensate", "fatty tetrahydropyrimidine"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

None

EMERGENCY OVERVIEW

RISK

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following ingestion, especially where pre-  existing organ (e.g. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality (death) rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern.  Considered an unlikely route of entry in commercial/industrial environments.  Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis.  

EYE

  Although the material is not thought to be an irritant, direct contact with the eye may produce transient discomfort characterized by tearing or conjunctival redness (as with windburn).  The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  The material is not thought to produce adverse health effects or skin irritation following contact (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.  The liquid may produce skin discomfort following prolonged contact. Defatting and/or drying of the skin may lead to dermatitis.  Many amine compounds are sensitizers and some are absorbed through intactskin.  

INHALED

  The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.  Inhalation hazard is increased at higher temperatures.  Inhalation of vapor may aggravate a pre-existing respiratory condition.  

CHRONIC HEALTH EFFECTS

  Principal routes of exposure are usually by skin contact/absorption and inhalation of vapor.  This material contains a polymer with a functional group considered to be of moderate concern. Aldehydes are reactive, soluble and are highly irritating. The lower (lighter) aldehydes attack exposed tissues and less soluble species can enter the lungs. Toxicity is lower for larger species because they are less easily absorbed by the body. However even large polymers with more than one medium-risk reactive group cannot be classified as a low risk polymer.