Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

UCB EBECRYL 3604

NFPA

PRODUCT USE

Ink manufacture.

SYNONYMS

TRPGDA, "acrylated epoxy", Polychem, "tripropylene glycol diacrylate",
"tripropyleneglycol diacrylate", "di acrylate ester monomer inhibited", "acrylic acid,
propylene(oxypropylene) ester", "2-propenoic acid, (1-methyl-1, 2-
ethandiyl)bis(oxy(methyl-2, 1-ethandiyl))", "2-propenoic acid, (1-methyl-1, 2-
ethandiyl)bis(oxy(methyl-2, 1-ethandiyl))", ester

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

May cause SENSITIZATION by skin contact.
Irritating to eyes, respiratory system and skin.
Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic
environment.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following ingestion, especially where pre-  existing organ (e.g. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality (death) rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern.  Considered an unlikely route of entry in commercial/industrial environments.  Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis.  

EYE

  This material can cause eye irritation and damage in some persons.  The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  This material can cause inflammation of the skin oncontact in some persons.  Skin contact is not thought to have harmful health effects, however the material may still produce health damage following entry through wounds, lesions or abrasions.  All multifunctional acrylates (MFA) produce skin disorders and sensitize the skin and inflammation. Vapors generated by the heat of milling may occur in sufficient concentration to produce inflammation. Because exposure to industrial aerosols of MFA includes exposure to resin systems, photo- initiators, solvents, hydrogen-transfer agents,  stabilizers, surfactants, fillers and polymerization inhibitors, poisoning may arise due to a range of chemical actions.  Irritation may not occur immediately but may be delayed 24-48 hours.  Sensitization reactions may appear suddenly after repeatedsymptom free exposures.  The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.  Bare unprotected skin should not be exposed to this material.  The material may accentuate any pre-existing dermatitis condition.  

INHALED

  If inhaled, this material can irritate the throat andlungs of some persons.  Although inhalation is not thought to produce harmful effects, the material may still produce health damage, especially where pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally confined to doses producing mortality (death) rather than those producing morbidity (disease, ill-  health).  Not normally a hazard due to non-volatile nature of product.  Inhalation hazard is increased at higher temperatures.  Acute effects from inhalation of high vapor concentrations may be chest and nasal irritation with coughing, sneezing, headache and even nausea.  No report of respiratory illness in humans as a result of exposure tomultifunctional acrylates has been found.  

CHRONIC HEALTH EFFECTS

  Skin contact with the material is more likely to cause a sensitization reaction in some persons compared to the general population.  

  Principal routes of exposure are usually by skin contact/eye contact and inhalation of vapor.  Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitized persons should not be allowed to work in situations where exposure may occur.  As with any chemical product, contact with unprotected bare skin; inhalation of vapor, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice.