Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

VINYL NEODECANOATE

NFPA

PRODUCT USE

Monomer reactant in the production of copolymer resins for latex paints.

SYNONYMS

C12-H22-O2, "neodecanoic acid ethenyl ester", "neodecanoic acid vinyl ester", "vinyl
trans-decanoate", "vinyl versatate", "Veova 10", "Exxar Neo 10 Vinyl Ester"

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

HARMFUL - May cause lung damage if swallowed.
Irritating to eyes and skin.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following ingestion, especially where pre-  existing organ (e.g. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality (death) rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern.  Considered an unlikely route of entry in commercial/industrial environments.  Ingestion may result in sore throat, abdominal pain, with central nervous system effects, headache, dizziness, drowsiness.  Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis; serious consequences may result. (ICSC13733).  Vinyl esters, when ingested, can cause damage to the brain and spinal cord, resulting in muscular weakness and loss of sensation in the limbs.  

EYE

  This material can cause eye irritation and damage in some persons.  The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.  

SKIN

  This material can cause inflammation of the skin oncontact in some persons.  Skin contact is not thought to have harmful health effects, however the material may still produce health damage following entry through wounds, lesions or abrasions.  Bare unprotected skin should not be exposed to this material.  Irritating to skin.  The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin. Repeated exposures may produce severe ulceration.  

INHALED

  Inhalation may produce health damage*.  The material is not thought to produce respiratory irritation (as classified using animal models). Nevertheless inhalation of the material, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.  Not normally a hazard due to non-volatile nature of product.  Inhalation hazard is increased at higher temperatures.  Inhalation of vapor may aggravate a pre-existing respiratory condition such as asthma, bronchitis, emphysema.  The main effects of simple esters are irritation, stupor and insensibility. Headache, drowsiness, dizziness, coma and behavioral changes may occur. Respiratory symptoms may include irritation, shortness of breath, rapid breathing, throat inflammation, bronchitis,  lung inflammation and pulmonary edema, sometimes delayed. Nausea, vomiting, diarrhea and cramps are observed. Liver and kidney damage may result from massive exposures.  Inhalation of vinyl esters is associated with damage to the nervous system. Exposure for extended periods can cause headache, dizziness, nausea, blurred vision and depression which is characterized by dizziness, drowsiness and headache, slowed reaction time, slurred speech and coma. Respiratory depression in serious cases of poisoning can cause death.  

CHRONIC HEALTH EFFECTS

  There is some evidence that inhaling this product is more likely to cause a sensitization reaction in some persons compared to the general population.  

  Primary route of exposure is usually by eye contact, skin contact with the material and inhalation of vapor.  Prolonged or repeated skin contact may cause drying with cracking,irritation and possible dermatitis following.  Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitized persons should not be allowed to work in situations where exposure may occur.  Exposure to vinyl esters for extended periods of time can cause nervous system damage, developmental defects and cancer. Fetal malformations and deaths can occur at concentrations below which the mother is affected; at higher levels, there is an increased risk of miscarriage.